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Carbon dioxide in Earth's atmosphere

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Carbon dioxide ( ) is an important trace gas in Earth's atmosphere. It is an integral part of the carbon cycle, a biogeochemical cycle in which carbon is exchanged between the Earth's oceans, soil, rocks and the biosphere. Plants and other photoautotrophs use solar energy to produce carbohydrate from atmospheric carbon dioxide and water by photosynthesis. Almost all other organisms depend on carbohydrate derived from photosynthesis as their primary source of energy and carbon compounds. absorbs and emits infrared radiation at wavelengths of 4.26 μm (2347 cm−1) (asymmetric stretching vibrational mode) and 14.99 μm (666 cm−1) (bending vibrational mode) and consequently is a greenhouse gas that plays a significant role in influencing Earth's surface temperature through the greenhouse effect.
Concentrations of in the atmosphere were as high as 4,000 parts per million (ppm, on a molar basis) during the Cambrian period about 500 million years ago to as low as 180 ppm during the Quaternary glaciation of the last two million years. Reconstructed temperature records for the last 420 million years indicate that atmospheric concentrations peaked at ~2000 ppm during the Devonian (∼400 Myrs ago) period, and again in the Triassic (220–200 Myrs ago) period. Global annual mean concentration has increased by more than 45% since the start of the Industrial Revolution, from 280 ppm during the 10,000 years up to the mid-18th century to 415 ppm as of May 2019. The present concentration is the highest for 14 million years. The increase has been attributed to human activity, particularly deforestation and the burning of fossil fuels.{{cite journal last=Etheridge first=D.M. author2=L.P. Steele author3=R.L. Langenfelds author4=R.J. Francey author5=J.-M. Barnola author6=V.I. Morgan year=1996 title=Natural and anthropogenic changes in atmospheric over the last 1000 years from air in Antarctic ice and firn journal=Journal of Geophysical Research volume=101 issue=D2 pages=4115–28 issn=0148-0227 doi=10.1029/95JD03410 bibcode = 1996JGR...101.4115E This increase of and other long-lived greenhouse gases in Earth's atmosphere has produced the current episode of global warming. Between 30% and 40% of the released by humans into the atmosphere dissolves into the oceans, wherein it forms carbonic acid and effects changes in the oceanic pH balance.

Current concentration

thumbrightThis visualization shows global carbon dioxide concentrations (colored squares) in parts per million by volume (ppmv).
File:Mauna Loa CO2 monthly mean concentration.svgthumbThe Keeling Curve of atmospheric concentrations measured at Mauna Loa Observatory
Carbon dioxide concentrations have shown several cycles of variation from about 180 parts per million during the deep glaciations of the Holocene and Pleistocene to 280 parts per million during the interglacial periods. Following the start of the Industrial Revolution, atmospheric concentration increased to over 400 parts per million and continues to increase, causing the phenomenon of global warming. Climate Change 2013 Working Group 1 website. , the average monthly level of in Earth's atmosphere exceeded 413 parts per million. The daily average concentration of atmospheric at Mauna Loa Observatory first exceeded 400 ppm on 10 May 2013 {{cite web url= title=Up-to-date weekly average at Mauna Loa accessdate = 2019-06-01 publisher = NOAA although this concentration had already been reached in the Arctic in June 2012.{{cite news url = newspaper = The Guardian accessdate = 11 May 2013 date = 1 June 2012 title = Greenhouse gas levels pass symbolic 400ppm milestone agency = Associated Press Each part per million by volume of in the atmosphere represents approximately 2.13 gigatonnes of carbon, or 7.82 gigatonnes of . As of 2018, constitutes about 0.041% by volume of the atmosphere, (equal to 410 ppm) which corresponds to approximately 3210 gigatonnes of , containing approximately 875 gigatonnes of carbon. The global mean concentration is currently rising at a rate of approximately 2 ppm/year and accelerating. The current growth rate at Mauna Loa is 2.50 ± 0.26 ppm/year (mean ± 2 std dev). As seen in the graph to the right, there is an annual fluctuation – the level drops by about 6 or 7 ppm (about 50 Gt) from May to September during the Northern Hemisphere's growing season, and then goes up by about 8 or 9 ppm. The Northern Hemisphere dominates the annual cycle of concentration because it has much greater land area and plant biomass than the Southern Hemisphere. Concentrations reach a peak in May as the Northern Hemisphere spring greenup begins, and decline to a minimum in October, near the end of the growing season.
Since global warming is attributed to increasing atmospheric concentrations of greenhouse gases such as and methane, scientists closely monitor atmospheric concentrations and their impact on the present-day biosphere. The National Geographic wrote that the concentration of carbon dioxide in the atmosphere is this high "for the first time in 55 years of measurement—and probably more than 3 million years of Earth history."{{cite web url = work = National Geographic accessdate = 2013-05-12 date = 2013-05-09 title = Climate Milestone: Earth's Level Passes 400 ppm first = Robert last = Kunzig The current concentration may be the highest in the last 20 million years.

Past concentration

thumb concentrations over the last 800,000 years
File:CO2 40k.pngthumbConcentration of atmospheric over the last 40,000 years, from the Last Glacial Maximum to the present day. The current rate of increase is much higher than at any point during the last deglaciation.
Carbon dioxide concentrations have varied widely over the Earth's 4.54 billion year history. It is believed to have been present in Earth's first atmosphere, shortly after Earth's formation. The second atmosphere, consisting largely of nitrogen and was produced by outgassing from volcanism, supplemented by gases produced during the late heavy bombardment of Earth by huge asteroids. A major part of carbon dioxide emissions were soon dissolved in water and incorporated in carbonate sediments.
The production of free oxygen by cyanobacterial photosynthesis eventually led to the oxygen catastrophe that ended Earth's second atmosphere and brought about the Earth's third atmosphere (the modern atmosphere) 2.4 billion years before the present. Carbon dioxide concentrations dropped from 4,000 parts per million during the Cambrian period about 500 million years ago to as low as 180 parts per million during the Quaternary glaciation of the last two million years.

Drivers of ancient-Earth carbon dioxide concentration

On long timescales, atmospheric concentration is determined by the balance among geochemical processes including organic carbon burial in sediments, silicate rock weathering, and volcanic degassing. The net effect of slight imbalances in the carbon cycle over tens to hundreds of millions of years has been to reduce atmospheric . On a timescale of billions of years, such downward trend appears bound to continue indefinitely as occasional massive historical releases of buried carbon due to volcanism will become less frequent (as earth mantle cooling and progressive exhaustion of internal radioactive heat proceed further). The rates of these processes are extremely slow; hence they are of no relevance to the atmospheric concentration over the next hundreds or thousands of years.
In billion-year timescales, it is predicted that plant, and therefore animal, life on land will die off altogether, since by that time most of the remaining carbon in the atmosphere will be sequestered underground, and natural releases of by radioactivity-driven tectonic activity will have continued to slow down. The loss of plant life would also result in the eventual loss of oxygen. Some microbes are capable of photosynthesis at concentrations of of a few parts per million and so the last life forms would probably disappear finally due to the rising temperatures and loss of the atmosphere when the sun becomes a red giant some four billion years from now.

Measuring ancient-Earth carbon dioxide concentration

thumbrightGraph of CO2 (green), reconstructed temperature (blue) and dust (red) from the Vostok ice core for the past 420,000 years
thumbrightCorrespondence between temperature and atmospheric during the last 800,000 years
The most direct method for measuring atmospheric carbon dioxide concentrations for periods before instrumental sampling is to measure bubbles of air (fluid or gas inclusions) trapped in the Antarctic or Greenland ice sheets. The most widely accepted of such studies come from a variety of Antarctic cores and indicate that atmospheric concentrations were about 260–280 ppmv immediately before industrial emissions began and did not vary much from this level during the preceding 10,000 years.{{cite webdate=June 1998first1=D.M.last1=Etheridgefirst2=L.P.last2=Steelefirst3=R.L.last3=Langenfeldsfirst4=R.J.last4=Franceyfirst5=JMlast5=Barnolafirst6=VIlast6=Morgantitle=Historical record derived from a spline fit (20-year cutoff) of the Law Dome DE08 and DE08-2 ice coresurl= Dioxide Information Analysis Centerpublisher=Oak Ridge National Laboratoryarchive-url= July 2012url-status=dead The longest ice core record comes from East Antarctica, where ice has been sampled to an age of 800,000 years. During this time, the atmospheric carbon dioxide concentration has varied between 180 and 210 ppm during ice ages, increasing to 280–300 ppm during warmer interglacials.{{cite journal author=Hileman B. title=Ice Core Record Extended: Analyses of trapped air show current at highest level in 650,000 years journal=Chemical & Engineering News volume=83 issue=48 pages=7 date=November 2005 url= issn=0009-2347 doi=10.1021/cen-v083n048.p007Vostok Ice Core Data, The beginning of human agriculture during the current Holocene epoch may have been strongly connected to the atmospheric increase after the last ice age ended, a fertilization effect raising plant biomass growth and reducing stomatal conductance requirements for intake, consequently reducing transpiration water losses and increasing water usage efficiency.
Various proxy measurements have been used to attempt to determine atmospheric carbon dioxide concentrations millions of years in the past. These include boron and carbon isotope ratios in certain types of marine sediments, and the number of stomata observed on fossil plant leaves.{{cite journal
author = Osborne, C.P.
author2=Beerling, D.J.
author-link2 = David Beerling
year = 2006
title = Nature's green revolution: the remarkable evolutionary rise of plants
journal = Philosophical Transactions of the Royal Society B: Biological Sciences
volume = 361
issue = 1465
pages = 173–94
doi = 10.1098/rstb.2005.1737
pmid = 16553316
pmc = 1626541
Phytane is a type of diterpenoid alkane. It is a breakdown product of chlorophyll and is now used to estimate ancient levels. Phytane gives both a continuous record of concentrations but it also can overlap a break in the record of over 500 million years.
There is evidence for high concentrations between 200 and 150 million years ago of over 3,000 ppm, and between 600 and 400 million years ago of over 6,000 ppm.IPCC: Climate Change 2001: The Scientific Basis In more recent times, atmospheric concentration continued to fall after about 60 million years ago. About 34 million years ago, the time of the Eocene–Oligocene extinction event and when the Antarctic ice sheet started to take its current form, was about 760 ppm,{{cite web title=New data helps unlock the secrets of Antarctic formation date=13 September 2009 url= and there is geochemical evidence that concentrations were less than 300 ppm by about 20 million years ago. Decreasing concentration, with a tipping point of 600 ppm, was the primary agent forcing Antarctic glaciation. Low concentrations may have been the stimulus that favored the evolution of C4 plants, which increased greatly in abundance between 7 and 5 million years ago. Based on an analysis of fossil leaves, Wagner et al.{{cite journal first = Friederike last = Wagner author2=Bent Aaby author3=Henk Visscher title = Rapid atmospheric changes associated with the 8,200-years-B.P. cooling event journal =Proc. Natl. Acad. Sci. USA volume = 99 issue = 19 year = 2002 pages = 12011–14 doi = 10.1073/pnas.182420699 pmc = 129389 pmid = 12202744 bibcode = 2002PNAS...9912011W argued that atmospheric concentrations during the last 7,000–10,000 year period were significantly higher than 300 ppm and contained substantial variations that may be correlated to climate variations. Others have disputed such claims, suggesting they are more likely to reflect calibration problems than actual changes in .{{cite journal first = Andreas last = Indermühle author2=Bernhard Stauffer author3=Thomas F. Stocker title = Early Holocene Atmospheric Concentrations journal = Science volume = 286 issue = 5446 year = 1999 pages = 1815 doi = 10.1126/science.286.5446.1815a doi-access = free Relevant to this dispute is the observation that Greenland ice cores often report higher and more variable values than similar measurements in Antarctica. However, the groups responsible for such measurements (e.g. H.J. Smith et al.{{cite journal first = H.J. last = Smith author2=M Wahlen author3=D. Mastroianni title = The concentration of air trapped in GISP2 ice from the Last Glacial Maximum-Holocene transition journal = Geophysical Research Letters volume = 24 issue = 1 year = 1997 pages = 1–4 doi = 10.1029/96GL03700 bibcode=1997GeoRL..24....1S) believe the variations in Greenland cores result from in situ decomposition of calcium carbonate dust found in the ice. When dust concentrations in Greenland cores are low, as they nearly always are in Antarctic cores, the researchers report good agreement between measurements of Antarctic and Greenland concentrations.

Atmospheric carbon dioxide and the greenhouse effect

thumbleftA pictogram of the greenhouse effect
Earth's natural greenhouse effect makes life as we know it possible and carbon dioxide plays a significant role in providing for the relatively high temperature that the planet enjoys. The greenhouse effect is a process by which thermal radiation from a planetary atmosphere warms the planet's surface beyond the temperature it would have in the absence of its atmosphere. A concise description of the greenhouse effect is given in the Intergovernmental Panel on Climate Change Fourth Assessment Report, "What is the Greenhouse Effect?" FAQ 1.3 – AR4 WGI Chapter 1: Historical Overview of Climate Change Science, IPCC Fourth Assessment Report, Chapter 1, p. 115: "To balance the absorbed incoming solar energy, the Earth must, on average, radiate the same amount of energy back to space. Because the Earth is much colder than the Sun, it radiates at much longer wavelengths, primarily in the infrared part of the spectrum (see Figure 1). Much of this thermal radiation emitted by the land and ocean is absorbed by the atmosphere, including clouds, and reradiated back to Earth. This is called the greenhouse effect."
Stephen H. Schneider, in Geosphere-biosphere Interactions and Climate, Lennart O. Bengtsson and Claus U. Hammer, eds., Cambridge University Press, 2001, , pp. 90–91.
E. Claussen, V.A. Cochran, and D.P. Davis, Climate Change: Science, Strategies, & Solutions, University of Michigan, 2001. p. 373.
A. Allaby and M. Allaby, A Dictionary of Earth Sciences, Oxford University Press, 1999, , p. 244. Without the greenhouse effect, the Earth's temperature would be about −18 Â°C (-0.4 Â°F) compared to Earth's actual surface temperature of approximately 14 Â°C (57.2 Â°F).
Carbon dioxide is believed to have played an important effect in regulating Earth's temperature throughout its 4.7 billion year history. Early in the Earth's life, scientists have found evidence of liquid water indicating a warm world even though the Sun's output is believed to have only been 70% of what it is today. It has been suggested by scientists that higher carbon dioxide concentrations in the early Earth's atmosphere might help explain this faint young sun paradox. When Earth first formed, Earth's atmosphere may have contained more greenhouse gases and concentrations may have been higher, with estimated partial pressure as large as , because there was no bacterial photosynthesis to reduce the gas to carbon compounds and oxygen. Methane, a very active greenhouse gas which reacts with oxygen to produce and water vapor, may have been more prevalent as well, with a mixing ratio of 10−4 (100 parts per million by volume).
File:Radiative forcing 1750-2011.svgthumbrightRadiative forcing drivers of climate change in year 2011, relative to pre-industrial (1750).
Though water is responsible for most (about 36-70%) of the total greenhouse effect, the role of water vapor as a greenhouse gas depends on temperature. On Earth, carbon dioxide is the most relevant, direct anthropologically influenced greenhouse gas. Carbon dioxide is often mentioned in the context of its increased influence as a greenhouse gas since the pre-industrial (1750) era. In the IPCC Fifth Assessment Report the increase in CO2 was estimated to be responsible for 1.82 W m−2 of the 2.63 W m−2 change in radiative forcing on Earth (about 70%).IPCC Fifth Assessment Report – Chapter 8: Anthropogenic and Natural Radiative Forcing.
The concept of atmospheric CO2 increasing ground temperature was first published by Svante Arrhenius in 1896. The increased radiative forcing due to increased CO2 in the Earth's atmosphere is based on the physical properties of CO2 and the non-saturated absorption windows where CO2 absorbs outgoing long-wave energy. The increased forcing drives further changes in Earth's energy balance and, over the longer term, in Earth's climate.

Atmospheric carbon dioxide and the carbon cycle

thumbleftThis diagram of the fast carbon cycle shows the movement of carbon between land, atmosphere, and oceans in billions of metric tons of carbon per year. Yellow numbers are natural fluxes, red are human contributions, white are stored carbon.
Atmospheric carbon dioxide plays an integral role in the Earth's carbon cycle whereby is removed from the atmosphere by some natural processes such as photosynthesis and deposition of carbonates, to form limestones for example, and added back to the atmosphere by other natural processes such as respiration and the acid dissolution of carbonate deposits. There are two broad carbon cycles on Earth: the fast carbon cycle and the slow carbon cycle. The fast carbon cycle refers to movements of carbon between the environment and living things in the biosphere whereas the slow carbon cycle involves the movement of carbon between the atmosphere, oceans, soil, rocks, and volcanism. Both cycles are intrinsically interconnected and atmospheric facilitates the linkage.
Natural sources of atmospheric include volcanic outgassing, the combustion of organic matter, wildfires and the respiration processes of living aerobic organisms. Man-made sources of include the burning of fossil fuels for heating, power generation and transport, as well as some industrial processes such as cement making. It is also produced by various microorganisms from fermentation and cellular respiration. Plants, algae and cyanobacteria convert carbon dioxide to carbohydrates by a process called photosynthesis. They gain the energy needed for this reaction from absorption of sunlight by chlorophyll and other pigments. Oxygen, produced as a by-product of photosynthesis, is released into the atmosphere and subsequently used for respiration by heterotrophic organisms and other plants, forming a cycle with carbon.
thumbright300pxAnnual flows from anthropogenic sources (left) into Earth's atmosphere, land, and ocean sinks (right) since year 1960. Units in equivalent gigatonnes carbon per year.
Most sources of emissions are natural, and are balanced to various degrees by similar sinks. For example, the decay of organic material in forests, grasslands, and other land vegetation - including the infrequent activity of forest fires - results in the release of about 400 gigatonnes of (containing 120 billion tonnes carbon) every year, while uptake by new growth on land nearly counteracts these releases. Although much in the early atmosphere of the young Earth was produced by volcanic activity, modern volcanic activity releases only 130 to 230 megatonnes of each year.{{cite journal author=Gerlach, T.M. title=Present-day emissions from volcanoes journal=Eos, Transactions, American Geophysical Union volume=72 issue=23 pages=249, 254–55 date=4 June 1991 doi=10.1029/90EO10192 bibcode=1991EOSTr..72..249. This small natural geologic source is also balanced by natural sinks, in the form of chemical and biological processes which remove from the atmosphere. By contrast, as of year 2019 the extraction and burning of geologic fossil carbon by humans releases over 30 gigatonnes of (9 billion tonnes carbon) each year.Friedlingstein, P., Jones, M., O'Sullivan, M., Andrew, R., Hauck, J., Peters, G., Peters, W., Pongratz, J., Sitch, S., Le Quéré, C. and 66 others (2019) "Global carbon budget 2019". Earth System Science Data, 11(4): 1783–1838. . 50px Material was copied from this source, which is available under a Creative Commons Attribution 4.0 International License. This larger disruption to the natural balance is responsible for recent growth in the atmospheric concentration.
Overall, there is a large natural flux of atmospheric into and out of the biosphere, both on land and in the oceans. In the pre-industrial era, each of these fluxes were in balance to such a degree that little net flowed between the land and ocean reservoirs of carbon, and little change resulted in the atmospheric concentration. From the human pre-industrial era to 1940, the terrestrial biosphere represented a net source of atmospheric (driven largely by land-use changes), but subsequently switched to a net sink with growing fossil carbon emissions. In 2012, about 57% of human-emitted , mostly from the burning of fossil carbon, was taken up by land and ocean sinks.{{cite journal vauthors=Canadell JG, Le Quéré C, Raupach MR title=Contributions to accelerating atmospheric growth from economic activity, carbon intensity, and efficiency of natural sinks journal=Proc. Natl. Acad. Sci. U.S.A. volume=104 issue=47 pages=18866–70 date=November 2007 pmid=17962418 pmc=2141868 doi=10.1073/pnas.0702737104 bibcode = 2007PNAS..10418866C display-authors=etal{{cite journal author1=Junling Huang author2=Michael B. McElroy url= Contemporary and Historical Budget of Atmospheric journal=Canadian Journal of Physics volume = 90 issue = 8 pages = 707–16 year=2012 doi=10.1139/p2012-033bibcode = 2012CaJPh..90..707H
The ratio of the increase in atmospheric to emitted is known as the airborne fraction (Keeling et al., 1995). This ratio varies in the short-term and is typically about 45% over longer (5-year) periods. Estimated carbon in global terrestrial vegetation increased from approximately 740 billion tons in 1910 to 780 billion tons in 1990. By 2009, acidity of the ocean surface increased about 30% due to uptake of emitted fossil .

Atmospheric carbon dioxide and photosynthesis

thumbuprightleftPhotosynthesis changes sunlight into chemical energy, splits water to liberate O2, and fixes CO2 into sugar.
Carbon dioxide in the Earth's atmosphere is essential to life and to most of the planetary biosphere. Over the course of Earth's geologic history concentrations have played a role in biological evolution. The first photosynthetic organisms probably evolved early in the evolutionary history of life and most likely used reducing agents such as hydrogen or hydrogen sulfide as sources of electrons, rather than water. Cyanobacteria appeared later, and the excess oxygen they produced contributed to the oxygen catastrophe, which rendered the evolution of complex life possible. In recent geologic times, low concentrations below 600 parts per million might have been the stimulus that favored the evolution of C4 plants which increased greatly in abundance between 7 and 5 million years ago over plants that use the less efficient C3 metabolic pathway. At current atmospheric pressures photosynthesis shuts down when atmospheric concentrations fall below 150 ppm and 200 ppm although some microbes can extract carbon from the air at much lower concentrations. Today, the average rate of energy capture by photosynthesis globally is approximately 130 terawatts, which is about six times larger than the current power consumption of human civilization. Photosynthetic organisms also convert around 100–115 billion metric tonnes of carbon into biomass per year.
Photosynthetic organisms are photoautotrophs, which means that they are able to synthesize food directly from and water using energy from light. However, not all organisms that use light as a source of energy carry out photosynthesis, since photoheterotrophs use organic compounds, rather than , as a source of carbon. In plants, algae and cyanobacteria, photosynthesis releases oxygen. This is called oxygenic photosynthesis. Although there are some differences between oxygenic photosynthesis in plants, algae, and cyanobacteria, the overall process is quite similar in these organisms. However, there are some types of bacteria that carry out anoxygenic photosynthesis, which consumes but does not release oxygen.
Carbon dioxide is converted into sugars in a process called carbon fixation. Carbon fixation is an endothermic redox reaction, so photosynthesis needs to supply both the source of energy to drive this process and the electrons needed to convert into a carbohydrate. This addition of the electrons is a reduction reaction. In general outline and in effect, photosynthesis is the opposite of cellular respiration, in which glucose and other compounds are oxidized to produce and water, and to release exothermic chemical energy to drive the organism's metabolism. However, the two processes take place through a different sequence of chemical reactions and in different cellular compartments.
Most organisms that utilize photosynthesis to produce oxygen use visible light to do so, although at least three use shortwave infrared or, more specifically, far-red radiation.

Effects of increased CO2 on plants and crops

A 1993 review of scientific greenhouse studies found that a doubling of concentration would stimulate the growth of 156 different plant species by an average of 37%. Response varied significantly by species, with some showing much greater gains and a few showing a loss. For example, a 1979 greenhouse study found that with doubled concentration the dry weight of 40-day-old cotton plants doubled, but the dry weight of 30-day-old maize plants increased by only 20%.
In addition to greenhouse studies, field and satellite measurements attempt to understand the effect of increased in more natural environments. In free-air carbon dioxide enrichment (FACE) experiments plants are grown in field plots and the concentration of the surrounding air is artificially elevated. These experiments generally use lower levels than the greenhouse studies. They show lower gains in growth than greenhouse studies, with the gains depending heavily on the species under study. A 2005 review of 12 experiments at 475–600 ppm showed an average gain of 17% in crop yield, with legumes typically showing a greater response than other species and C4 plants generally showing less. The review also stated that the experiments have their own limitations. The studied levels were lower, and most of the experiments were carried out in temperate regions. Satellite measurements found increasing leaf area index for 25% to 50% of Earth's vegetated area over the past 35 years (i.e., a greening of the planet), providing evidence for a positive CO2 fertilization effect.
A 2017 Politico article states that increased levels may have a negative impact on the nutritional quality of various human food crops, by increasing the levels of carbohydrates, such as glucose, while decreasing the levels of important nutrients such as protein, iron, and zinc. Crops experiencing a decrease in protein include rice, wheat, barley and potatoes.

Atmospheric carbon dioxide and the oceanic carbon cycle

thumbAir-sea exchange of
The Earth's oceans contain a large amount of in the form of bicarbonate and carbonate ions—much more than the amount in the atmosphere. The bicarbonate is produced in reactions between rock, water, and carbon dioxide. One example is the dissolution of calcium carbonate:
+ + ⇌ + 2

Reactions like this tend to buffer changes in atmospheric . Since the right side of the reaction produces an acidic compound, adding on the left side decreases the pH of seawater, a process which has been termed ocean acidification (pH of the ocean becomes more acidic although the pH value remains in the alkaline range). Reactions between and non-carbonate rocks also add bicarbonate to the seas. This can later undergo the reverse of the above reaction to form carbonate rocks, releasing half of the bicarbonate as . Over hundreds of millions of years, this has produced huge quantities of carbonate rocks.
Ultimately, most of the emitted by human activities will dissolve in the ocean;{{cite journal author=Archer, D. title=Fate of fossil fuel in geologic time journal=J. Geophys. Res. volume=110 year=2005 doi=10.1029/2004JC002625 bibcode=2005JGRC..11009S05A however, the rate at which the ocean will take it up in the future is less certain.
Even if equilibrium is reached, including dissolution of carbonate minerals, the increased concentration of bicarbonate and decreased or unchanged concentration of carbonate ion will give rise to a higher concentration of un-ionized carbonic acid and dissolved . This , along with higher temperatures, would mean a higher equilibrium concentration of in the air.

Anthropogenic CO2 emissions

File:M15-162b-EarthAtmosphere-CarbonDioxide-FutureRoleInGlobalWarming-Simulation-20151109.jpgthumbupright=1.5rightCO2 in Earth's atmosphere if half of anthropogenic CO2 emissions are not absorbed. (NASA computer simulation)
While absorption and release is always happening as a result of natural processes, the recent rise in levels in the atmosphere is known to be mainly due to human (anthropogenic) activity.e.g. {{cite journal last1=Gosh last2=Brand title=Stable isotope ratio mass spectrometry in global climate change research journal=International Journal of Mass Spectrometry volume=228 issue=1 pages=1–33 year=2003 url= doi=10.1016/S1387-3806(03)00289-6 first1=Prosenjit first2=Willi A. quote=Global change issues have become significant due to the sustained rise in atmospheric trace gas concentrations ( , , ) over recent years, attributable to the increased per capita energy consumption of a growing global population.bibcode = 2003IJMSp.228....1G citeseerx= There are four ways human activity, especially fossil fuel burning, is known to have caused the rapid increase in atmospheric over the last few centuries:
  • Various national statistics accounting for fossil fuel consumption, combined with knowledge of how much atmospheric is produced per unit of fossil fuel (e.g. liter of gasoline).
  • By examining the ratio of various carbon isotopes in the atmosphere. The burning of long-buried fossil fuels releases containing carbon of different isotopic ratios to those of living plants, enabling distinction between natural and human-caused contributions to concentration.
  • Higher atmospheric concentrations in the Northern Hemisphere, where most of the world's population lives (and emissions originate from), compared to the southern hemisphere. This difference has increased as anthropogenic emissions have increased.
  • Atmospheric O levels are decreasing in Earth's atmosphere as it reacts with the carbon in fossil fuels to form .
Burning fossil fuels such as coal, petroleum, and natural gas is the leading cause of increased anthropogenic ; deforestation is the second major cause. In 2010, 9.14 gigatonnes of carbon (GtC, equivalent to 33.5 gigatonnes of or about 4.3 ppm in Earth's atmosphere) were released from fossil fuels and cement production worldwide, compared to 6.15 GtC in 1990. In addition, land use change contributed 0.87 GtC in 2010, compared to 1.45 GtC in 1990. In 1997, human-caused Indonesian peat fires were estimated to have released between 13% and 40% of the average annual global carbon emissions caused by the burning of fossil fuels. In the period 1751 to 1900, about 12 GtC were released as to the atmosphere from burning of fossil fuels, whereas from 1901 to 2013 the figure was about 380 GtC.Calculated from file global.1751_2013.csv in from the Carbon Dioxide Information Analysis Center.
The Integrated Carbon Observation System (ICOS) continuously releases data about emissions, budget and concentration at individual observation stations.
{ >
File:Global Carbon Emissions.svgGlobal fossil carbon emissions 1800–2014
File:TOMS indonesia smog lrg.jpgFalse-color image of smoke and ozone pollution from Indonesian fires, 1997
File:Biosphere CO2 Flux 08072006.gifBiosphere flux in the northern hemisphere summer (NOAA Carbon Tracker)
File:Biosphere CO2 Flux 23122006.gifBiosphere flux in the northern hemisphere winter (NOAA Carbon Tracker)

Ongoing measurements of atmospheric CO2

thumbCarbon Dioxide observations from 2005 to 2014 showing the seasonal variations and the difference between northern and southern hemispheres
The first reproducibly accurate measurements of atmospheric CO2 were from flask sample measurements made by Dave Keeling at Caltech in the 1950s.The Early Keeling Curve, SIO. Accessed 4 March 2016 A few years later in March 1958 the first ongoing measurements were started by Keeling at Mauna Loa. Measurements at Mauna Loa have been ongoing since then. Now measurements are made at many sites globally. Additional measurement techniques are also used as well. Many measurement sites are part of larger global networks. Global network data are often made publicly available on the conditions of proper acknowledgment according to the respective data user policies.
There are several surface measurement (including flasks and continuous in situ) networks including NOAA/ERSL,NOAA CCGG page Retrieved 2 March 2016 WDCGG,WDCGG webpage Retrieved 2 March 2016 and RAMCES.RAMCES webpage Retrieved 2 March 2016 The NOAA/ESRL Baseline Observatory Network, and the Scripps Institution of Oceanography NetworkCDIAC CO2 page Retrieved 9 February 2016 data are hosted at the CDIAC at ORNL. The World Data Centre for Greenhouse Gases (WDCGG), part of GAW, data are hosted by the JMA. The Reseau Atmospherique de Mesure des Composes an Effet de Serre database (RAMCES) is part of IPSL.
From these measurements, further products are made which integrate data from the various sources. These products also address issues such as data discontinuity and sparseness. GLOBALVIEW-CO2 is one of these products.GLOBALVIEW-CO2 information page. Retrieved 9 February 2016
Ongoing ground-based total column measurements began more recently. Column measurements typically refer to an averaged column amount denoted XCO2, rather than a surface only measurement. These measurements are made by the TCCON. These data are also hosted on the CDIAC, and made publicly available according to the data use policy.TCCON data use policy webpage Retrieved 9 February 2016
Satellite measurements are also a recent addition to atmospheric XCO2 measurements. SCIAMACHY aboard ESA's ENVISAT made global column XCO2 measurements from 2002 to 2012. AIRS aboard NASA's Aqua satellite makes global XCO2 measurements and was launched shortly after ENVISAT in 2012. More recent satellites have significantly improved the data density and precision of global measurements. Newer missions have higher spectral and spatial resolutions. JAXA's GOSAT was the first dedicated GHG monitoring satellite to successfully achieve orbit in 2009. NASA's OCO-2 launched in 2014 was the second. Various other satellites missions to measure atmospheric XCO2 are planned.

See also

  • Atmospheric carbon cycle
  • Carbon cycle
  • Global temperature record
  • Keeling Curve

External links

  • Current global map of carbon dioxide concentrations in the atmosphere
  • Current global map of the partial pressure of carbon dioxide at the ocean surface
  • Current global map of the sea-air carbon dioxide flux density
  • Global Carbon Dioxide Circulation (NASA; 13 December 2016)
  • Video (03:10) – A Year in the Life of Earth's CO2 (NASA; 17 November 2014)

Category:Atmosphere of Earth
Category:Carbon dioxide
Category:Greenhouse gases
fr:Dioxyde de carbone#CO2 dans l'atmosphère terrestre

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